Bright color screens
A subtle combination of light-emitting semiconducting polymers and small photocommutable molecules to fabricate organic electroluminescent transistors that operate under remote optical control, thereby paving the way for next-generation multifunctional optoelectronic devices.
Researchers at the Nanochemistry Laboratory of the Institute of Supramolecular Science and Engineering (University of Strasbourg & CNRS), in collaboration with University College London (United Kingdom) and Humboldt University of Berlin (Germany), have shown that a subtle combination of light-emitting semiconducting polymers and small photocommutable molecules can be used to fabricate organic electroluminescent transistors that operate under remote optical control, thereby paving the way for a new generation of multifunctional optoelectronic devices.
Organic light-emitting transistors are widely recognized as key components in many optoelectronic applications. However, integrating multiple functions into a single electronic device remains a major challenge in this technology sector. Furthermore, the new generation of displays requires the encoding of high-density visual information into individual, extremely small pixels.
A team of researchers from Strasbourg, London, and Berlin has taken a major step forward by creating the first organic electroluminescent transistor that can be controlled remotely by light itself. They combined a custom-designed molecule—which acts as a miniaturized optical switch—with a light-emitting semiconducting polymer. When illuminated with ultraviolet and visible light, the molecular switch reversibly changes its electronic properties. As a result, the device’s electrical and optical response can be simultaneously modulated by light, which serves as a remote optical control.
However, a device capable of producing only a single color is not sufficient for everyday applications, such as color displays. By selecting suitable photo-switchable molecules and mixing them with appropriate light-emitting polymers, the researchers have demonstrated that this new type of organic electroluminescent transistor can emit light in the range of the three primary colors (red, green, and blue), thereby covering the entire visible spectrum.
The disruptive potential of this approach has been demonstrated by writing and erasing spatially defined emitting patterns (such as a letter) within a single device using a laser beam, that is, through a non-invasive, mask-free process with a response time on the order of microseconds and a spatial resolution of a few micrometers, thereby surpassing even the best “Retina” displays. Clearly, these results represent a major breakthrough that offers numerous possibilities for smart displays, active optical memories, and optically controlled logic circuits.
Reference:
Optically Switchable Organic Light-Emitting Transistors
Lili Hou, Xiaoyan Zhang, Giovanni F. Cotella, Giuseppe Carnicella, Martin Herder, Bernd M. Schmidt, Michael Pätzel, Stefan Hecht, Franco Cacialli & Paolo Samorì
Nature Nanotechnology, 2019
DOI: 10.1038/s41565-019-0370-9
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